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34513-98-9 - Ruthenium(III) nitrosylnitrate solution, Ru 1.5% w/v - 12630 - Alfa Aesar

12630 Ruthenium(III) nitrosylnitrate solution, Ru 1.5% w/v

CAS Number
34513-98-9
Synonyms

Size Price ($) Quantity Availability
50ml 82.71
250ml 357.41
1000ml 1086.12
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Ruthenium(III) nitrosylnitrate solution, Ru 1.5% w/v

MDL
MFCD00016313
EINECS
252-068-8

Chemical Properties

Formula
N4O10Ru
Formula Weight
317.09
Form
Liquid
Density
1.07
Solubility
Miscible with cold water.

Applications

Ruthenium(III) nitrosyl nitrate used as a catalyst in various reactions namely hydrogenation, carbonylation, hydrosilylation, hydrofomylation, C-X coupling (eg Heck, Suzuki, Stille) and chiral catalysis reactions. It is also used in the production of thick-film resistors.

Notes

1.1Incompatible with reducing agents, phosphorus, sulfur and organic matter.

Literature References

Rathgeb, A.; Bohm, A.; Novak, M. S.; Gavriluta, A.; Domotor, O.; Tommasino, J. B.; Enyedy, E. A.; Shova, S.; Meier, S.; Jakupec, M. A.; Luneau, D.; Arion, V. B. Ruthenium-Nitrosyl Complexes with Glycine, l-Alanine, l-Valine, l-Proline, d-Proline, l-Serine, l-Threonine, and l-Tyrosine: Synthesis, X-ray Diffraction Structures, Spectroscopic and Electrochemical Properties, and Antiproliferative Activity. Inorg. Chem. 2014, 53 (5), 2718-2729.

Lopes, L. M.; Garcia, A. R.; Fidalgo, A.; Ilharco, L. M. Encapsulation of Ruthenium Nitrosylnitrate and DNA Purines in Nanostructured Sol-Gel Silica Matrices. Langmuir 2009, 25 (17), 10243-10250.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H314

May intensify fire; oxidizer. Causes severe skin burns and eye damage.

Precautionary Statements: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes

Recommended

  • 11264

    Lanthanum(III) oxide, REacton®, 99.99% (REO)
  • 11403

    Calcium carbonate, 99.5% (metals basis)
  • 11413

    Perrhenic acid, 75-80% aq. soln.
  • 13024

    Silicon(IV) oxide, 99.5%
  • 13418

    Lithium carbonate, 99%

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