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32005-36-0 - Bis(dibenzylideneacetone)palladium(0) - 12764 - Alfa Aesar

12764 Bis(dibenzylideneacetone)palladium(0)

CAS Number
32005-36-0
Synonyms

Size Price ($) Quantity Availability
0.25g 20.00
1g 45.00
5g 152.44
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Bis(dibenzylideneacetone)palladium(0)

MDL
MFCD00051942

Chemical Properties

Formula
C34H28O2Pd
Formula Weight
575.00
Form
Powder, Packaged under argon
Melting point
135° dec.
Sensitivity
Air & Moisture Sensitive
Solubility
Slightly soluble in CH{2}Cl{2}, CHCl{3} and benzene.Soluble in dichloromethane, chloroform, 1,2-dichloroethane, acetone, acetonitrile and benzene. Insoluble in water.

Applications

Hydrogenation, isomerization, carbonylation, oxidation, C-C bond formation.Bis(dibenzylideneacetone)palladium(0) is used as a reagent for the preparation of allylic substituted cyclopentadienes. It acts as a homogeneous catalyst as well as in the alkylation of allyl acetates by various nucleophiles. Further, it is used in Suzuki reaction.

Notes

Incompatible with strong oxidizing agents.

Literature References

Chan, K. S.; Fu, H. Y.; Yu, J. Q. Palladium(II)-Catalyzed Highly Enantioselective C-H Arylation of Cyclopropylmethylamines. J. Am. Chem. Soc. 2015, 137 (5), 2042-2046.

Son, S.; Lee, H.; Kwak, C.; Lee, J.; Ahn, H.; Chung, M. A Study of Phosphorescent Light Emitting Using Cyclometalated Pt(II) Complexes. J. Nanosci. Nanotechnol. 2015, 15 (7), 5338-5341.

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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