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12778 cis-Bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate, Ru 19% min

CAS Number
609844-11-3
Synonyms
cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate
Ru(bpy)2Cl2•H2O

Stock No. Size Price ($) Quantity Availability
12778-03 1g 105.00
12778-06 5g 471.00
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cis-Bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate, Ru 19% min

MDL
MFCD00012040

Chemical Properties

Formula
C20H16Cl2N4Ru•2H2O
Formula Weight
520.38 (484.35anhy)
Form
Crystalline
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

cis-Bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate is used in the preparation of [Ru(m-) 2,2'-bipyridine)3]2+(PF6-)2. It is also involved in the preparation of an intermediate for the development of nanocomposite junctions with gold nanoparticles.

Notes

Incompatible with strong oxidizing agents, halogens and alkali metals.

Literature References

Li, P.; Jin, Z.; Zhao, M.; Xu, Y.; Guo, Y.; Xiao, D. Self-enhanced electrogenerated chemiluminescence of ruthenium(ii) complexes conjugated with Schiff bases. Dalton Trans. 2015, 44 (5), 2208-2216.

Leem, G.; Morseth, Z. A.; Puodziukynaite, E.; Jiang, J.; Fang, Z.; Gilligan, A. T.; Reynolds, J. R.; Papanikolas, J. M.; Schanze, K. S. Light Harvesting and Charge Separation in a pi-Conjugated Antenna Polymer Bound to TiO2. J. Phys. Chem. C 2014, 118 (49), 28535-28541.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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