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13759-83-6 - Samarium(III) nitrate hexahydrate, 99.9% (REO) - 12906 - Alfa Aesar

12906 Samarium(III) nitrate hexahydrate, 99.9% (REO)

CAS Number
13759-83-6
Synonyms

Size Price ($) Quantity Availability
25g 52.80
100g 150.00
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Samarium(III) nitrate hexahydrate, 99.9% (REO)

MDL
MFCD00149857
EINECS
233-798-6

Chemical Properties

Formula
Sm(NO3)3•6H2O
Formula Weight
444.45 (336.36anhy)
Form
Crystalline
Melting point
78-79°
Density
2.375
Sensitivity
Hygroscopic
Solubility
Soluble in water and acetonitrile.

Applications

It is used in NMR spectroscopy for spectra resolution and is used for doping purpose. It is also used as a chemical reagent.

Notes

Hygroscopic in nature and it should be stored below 5°C temperature.

Literature References

Stoscup, J. A.; Staples, R. J.; Biros, S. M. Crystal structure of a samarium(III) nitrate chain cross-linked by a bis-carbamoylmethylphosphine oxide ligand. Acta Crystallogr. Sect. E.-Struct. Rep. 2014, 70 (10), 188-191.

Tang, N.; Zhao, Y.; He, L.; Yuan, W. L.; Tao, G. H. Long-lived luminescent soft materials of hexanitratosamarate(III) complexes with orange visible emission. Dalton Trans. 2015, 44 (19), 8816-8823.

Vallejos, S.; Muñoz, A.; Ibeas, S.; Serna, F.; García, F. C.; García, J. M. Selective and sensitive detection of aluminium ions in water via fluorescence “turn-on” with both solid and water soluble sensory polymer substrates. J. hazard. mater. 2014, 276, 52-57.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H303-H315-H319-H335

May intensify fire; oxidizer. May be harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P221-P210v-P220-P305+P351+P338-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat Keep/Store away from clothing/combustible materials. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2846.90
TSCA
Yes
RTECS
VP3150000

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