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7783-49-5 - Zinc fluoride, Puratronic®, 99.995% (metals basis) - 12986 - Alfa Aesar

12986 Zinc fluoride, Puratronic®, 99.995% (metals basis)

CAS Number
7783-49-5
Synonyms

Size Price ($) Quantity Availability
5g 59.60
25g 192.00
100g 539.00
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Zinc fluoride, Puratronic®, 99.995% (metals basis)

MDL
MFCD00011298
EINECS
232-001-9

Chemical Properties

Formula
F2Zn
Formula Weight
103.37
Form
Powder
Melting point
872°
Boiling Point
1500°
Density
4.95
Solubility
Sparingly soluble in hydrochloric acid, nitric acid, and ammonium hydroxide.

Applications

It is widely used in fluorination of organic compounds, as additive of electrolytic aluminum and also in electroplating baths. It is used in preserving food, manufacture of flux, oxygen-sensitive applications such as metal production, glasses, enamels, fabrics and plastics. It is also used in oil refining, manufacture of pharmaceuticals, manufacture phosphors for fluorescent electric lights, and floor coverings.

Notes

Hygroscopic. Hydrolysis occurs in hot water to produce zinc hydroxyfluoride.

Literature References

Guo, Y.; Wuttke, S.; Vimont, A.; Daturi, M.; Teinz, K.; Kemnitz, E. Novel sol-gel prepared zinc fluoride: synthesis, characterisation and acid-base sites analysis. J. Mater. Chem. 2012, 22, 14587-14593.

Sattler, W.; Ruccolo, S.; Parkin, G. Synthesis, Structure, and Reactivity of a Terminal Organozinc Fluoride Compound: Hydrogen Bonding, Halogen Bonding, and Donor-Acceptor Interactions. J. Am. Chem. Soc. 2013, 135 (50), 18714-18717.

Zhang, Z. G.; Wang, H.; and Zhu, M. Hydrogen release from sodium borohydrides at low temperature by the addition of zinc fluoride. Int. J. Hydrogen Energ. 2011, 36 (14), 8203-8208.

Sharma, Y. K.; Surana, S. S. L.; Dubedi, R. P.; Joshi, V. Spectroscopic and radiative properties of Sm 3+ doped zinc fluoride borophosphate glasses. Mater. Sci. Eng. B 2005, 119 (2), 131-135.

GHS Hazard and Precautionary Statements

Hazard Statements: H318-H315-H335

Causes serious eye damage. Causes skin irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280-P305+P351+P338-P304+P340-P310-P362-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,10136
Harmonized Tariff Code
2826.19
TSCA
Yes
RTECS
ZH3500000

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