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13060 Octacarbonyldicobalt, stab. with 1-5% hexane

CAS Number
10210-68-1
Synonyms
Cobalt carbonyl
Cobalt tetracarbonyl

Stock No. Size Price ($) Quantity Availability
13060-88 2.5g 66.30
13060-14 25g 162.00
13060-22 100g 578.00
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Octacarbonyldicobalt, stab. with 1-5% hexane

MDL
MFCD00016024
EINECS
233-514-0

Chemical Properties

Formula
C8Co2O8
Formula Weight
341.95
Form
Crystalline
Melting point
ca 51° dec.
Flash Point
-13°(-9°F)
Density
1.73
Storage & Sensitivity
Store under Nitrogen. Store at -20°C. Air Sensitive.
Solubility
Insoluble in water. Soluble in alcohol, ether and carbon disulfideSoluble in ether, naphtha and carbon disulfide. Slightly soluble in alcohol. Insoluble in water.

Applications

As a catalyst in oxo process, and in high-purity cobalt saltsOctacarbonyldicobalt is used as a catalyst for hydroformylation. It plays an important role in promoting both the Nicholas reaction and the Pauson-Khand reaction. It acts as a reagent and catalyst in organometallic chemistry and organic synthesis. It is involved as an alkyne protecting group.

Notes

Air sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Ruan, Z.; Rong, W.; Li, Q.; Li, Z. Oxygen as the growth enhancer of carbon nanotubes in solid-state pyrolysis of organometallic precursors. Carbon 2015, 87, 338-346.

Ruan, Z.; Rong, W.; Li, Q.; Li, Z. Synthesis and Solid-State Pyrolysis Behavior of POSS Containing Organometallic Polymer with Dicobalt Hexacarbonyl in the Side Chain. J. Inorg. Organomet. Polym. Mater. 2015, 25 (1), 98-106.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H332-H304-H317-H336-H350-X

Harmful if swallowed. Harmful if inhaled. May be fatal if swallowed and enters airways. May cause an allergic skin reaction. May cause drowsiness or dizziness. May cause cancer.

Precautionary Statements: P201-P202-P235+P410-P264b-P270-P271-P272-P280g-P281-P301+P310-P302+P352-P304+P340-P308+P313-P330-P331-P333+P313-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep cool. Protect from sunlight. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. Do NOT induce vomiting. If skin irritation or rash occurs: Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.2
Packing Group
II
Harmonized Tariff Code
2853.90
TSCA
Yes
RTECS
GG0300000

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