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13151 Nitronium hexafluorophosphate

CAS Number
19200-21-6
Synonyms

Stock No. Size Price ($) Quantity Availability
13151-06 5g 121.00
13151-14 25g 426.00
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Nitronium hexafluorophosphate

MDL
MFCD00031520
EINECS
242-872-7

Chemical Properties

Formula
NO2PF6
Formula Weight
190.97
Form
Crystalline
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in dichloromethane and nitroethane.

Applications

Nitronium hexafluorophosphate is a nitrating reagent used in the nitration of alkanes such as methane, ethane, propane, n-butane, isobutane, neopentane and cyclohexane.

Notes

Air and moisture sensitive. Hygroscopic. Incompatible with acids and water.

Literature References

Lu, Y.; Jiang, Y.; Wu, H.; Chen, W. Ferrocene-Functionalized Graphene Oxide Nanosheets: Efficient Electronic Communication between Ferrocene Centers across Graphene Nanosheets. Electrochim. Acta 2015, 156, 267-273.

Löwe, H.; Wei, G.; Jiang, M.; Hofmann, C.; Kost, H. J.; Schütt, C. Multi-step processing in a microstructured flow reactor: direct nitration of propane-a proof of principle. Green Process. Synth. 2012, 1 (5), 439-448.

GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2812.90
TSCA
Yes

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