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13617 Tin(IV) iodide, ultra dry, 99.998% (metals basis)

CAS Number
7790-47-8
Synonyms

Stock No. Size Price ($) Quantity Availability
13617-06 5g 124.00
13617-14 25g 536.00
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Tin(IV) iodide, ultra dry, 99.998% (metals basis)

MDL
MFCD00036272
EINECS
232-208-4

Chemical Properties

Formula
SnI4
Formula Weight
626.31
Form
Powder, Ampouled under argon
Melting point
ca 143°
Boiling Point
340°
Density
4.46
Refractive Index
2.106
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in alcohol, benzene, carbon disulfide, chloroform and ether.

Applications

Tin(IV) iodide is used in the preparation of tin(IV) oxide and tin(II) oxide. It reacts with hydroiodic acid to get rare tin hexaiodide. It forms tetraiodobis triphenylphosphine tin complexes by reacting with triphenylphosphine, which finds application in toothpaste formulation. Further, it acts as analytical reagents and also used in organic synthesis.

Notes

Moisture sensitive. Incompatible with strong oxidizing agents and strong bases.

Literature References

Lewis, D. J.; Kevin, P.; Bakr, O.; Muryn, C. A.; Malik, M. A.; O'Brien, P. Routes to tin chalcogenide materials as thin films or nanoparticles: a potentially important class of semiconductor for sustainable solar energy conversion. Inorg. Chem. Front. 2015, 1 (8), 577-598.

Maughan, A. E.; Kurzman, J. A.; Neilson, J. R. Hybrid Inorganic-Organic Materials with an Optoelectronically Active Aromatic Cation:(C7H7)2SnI6 and C7H7PbI3. Inorg. Chem. 2015, 54 (1), 370-378.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,8777
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2827.60
TSCA
Yes

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