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13930 Dichlorobis(triphenylphosphine)nickel(II), 98%

CAS Number
14264-16-5
Synonyms
Bis(triphenylphosphine)nickel(II) chloride
Bis(triphenylphosphine)dichloronickel(II)

Stock No. Size Price ($) Quantity Availability
13930-09 10g 34.40
13930-18 50g 126.00
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Dichlorobis(triphenylphosphine)nickel(II), 98%

MDL
MFCD00009592
EINECS
238-154-8

Chemical Properties

Formula
NiCl2[P(C6H5)3]2
Formula Weight
654.18
Form
Crystalline powder
Melting point
ca 225° dec.
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Dichlorobis(triphenylphosphine)nickel(II) is used as a catalyst for cross-coupling of Grignard reagents, hydrosilylations, hydrogenation and polymerization.

Notes

Store at -20°C. It is sensitive to moisture, air and heat. Handle and store under inert gas. Hygroscopic in nature.

Literature References

Daniel R. Palo.; Can Erkey. Solubility of Dichlorobis(triphenylphosphine)nickel(II) in Supercritical Carbon Dioxide. J. Chem. Eng. 1998, 43 (1), 47-48.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H317-H350

Harmful if swallowed. May cause an allergic skin reaction. May cause cancer.

Precautionary Statements: P201-P261-P280-P301+P312a-P405-P501a

Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.39
TSCA
Yes
RTECS
QR6170000

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