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13932 Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

CAS Number
14647-23-5
Synonyms
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

Stock No. Size Price ($) Quantity Availability
13932-04 2g 37.10
13932-09 10g 116.00
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Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II), 98%

MDL
MFCD00013313

Chemical Properties

Formula
NiCl2[(C6H5)2PCH2CH2P(C6H5)2]
Formula Weight
528.02
Form
Orange-red to brown powder
Melting point
263-265°
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive.

Literature References

Bryan E Barton; C Matthew Whaley; Thomas B Rauchfuss; Danielle L Gray. Nickel-iron dithiolato hydrides relevant to the [NiFe]-hydrogenase active site. Journal of the American Chemical Society. 2009, 131 (20), 6942-6943.

Yusuke Ueki; Hideto Ito; Ippei Usui; Bernhard Breit. Formation of quaternary carbon centers by highly regioselective hydroformylation with catalytic amounts of a reversibly bound directing group. Chemistry: A European Journal. 2011, 17 (31), 8555-8558.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H317-H319-H334-H335-H350

Harmful if swallowed. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause cancer.

Precautionary Statements: P201-P202-P264b-P270-P271-P272-P280-P281-P285-P301+P312-P302+P352-P304+P340-P305+P351+P338-P308+P313-P330-P333+P313-P342+P311-P362-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. If skin irritation or rash occurs: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.39
TSCA
No

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