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14036 Hydrobromic acid, 48% w/w aq. soln.

CAS Number
10035-10-6
Synonyms
Hydrogen bromide

Stock No. Size Price ($) Quantity Availability
14036-AT 940ml 65.00
14036-AZ *4x940ml 131.00
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Hydrobromic acid, 48% w/w aq. soln.

MDL
MFCD00011323
EINECS
233-113-0

Chemical Properties

Formula
HBr
Formula Weight
80.92
Form
Liquid
Density
1.490
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Miscible with water, alcohol and organic solvents.

Applications

Hydrobromic acid is an indispensable raw material for organic intermediates, inorganic pharmaceuticals, photosensitive materials, dyes and medicines. It is also used in the production of bromine compounds. It is used as an important agent in the industrial processes of isomerization, polymerization, hydration and dehydration and esterification reactions. It plays an essential role for the extraction of mercury from the cinnebar ore.

Notes

Air and light sensitive. Incompatible with strong bases, strong oxidizing agents, ammonia, ozone, fluorine, potassium permanganate, amines, alcohols and metals.

Literature References

Preferred reagent for the non-hydrogenolytic cleavage of the N-benzyloxycarbonyl (Cbz, Z) group in peptide synthesis: J. Org. Chem., 17, 1564 (1952). For peptide reagents, see Appendix 6.

Used in combination with Paraformaldehyde, A11313, or 1,3,5-Trioxane, A15639, for the bromomethylation of aromatics: J. Org. Chem., 58, 1262 (1993); Synlett, 55 (1989). For N-bromomethylation of phthalimide and other imides, see: Synlett, 933 (1994).

For use in the bromoacetoxylation of (S)-(+)-1,2-Propanediol, B21773, as an example of the conversion of chiral vic-diols to epoxides with retention of configuration, see: J. Chem. Soc., Perkin 1, 1214 (1973); Org. Synth. Coll., 7, 356 (1990).

Cai, X.; Li, Y.; Yue, D.; Yi, Q.; Li, S.; Shi, D.; Gu, Z. Reversible PEGylation and Schiff-base linked imidazole modification of polylysine for high-performance gene delivery. J. Mater. Chem. B 2015, 3 (8), 1507-1517.

Wang, Q. M.; Gao, Z.; Liu, S.; Fan, B.; Kang, L.; Huang, W.; Jin, M. Hybrid polymeric micelles based on bioactive polypeptides as pH-responsive delivery systems against melanoma. Biomaterials 2014, 35 (25), 7008-7021.

GHS Hazard and Precautionary Statements

Hazard Statements: H290-H314-H335

May be corrosive to metals. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P234-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P390-P501c

Keep only in original container. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,4778
Beilstein
3587158
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2811.19
TSCA
Yes
RTECS
MW3850000

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