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14703 Silicon(IV) acetate

CAS Number
562-90-3
Synonyms
Silicon tetraacetate

Stock No. Size Price ($) Quantity Availability
14703-18 50g 130.00
14703-30 250g 488.00
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Silicon(IV) acetate

MDL
MFCD00026184
EINECS
209-239-7

Chemical Properties

Formula
Si(OOCCH3)4
Formula Weight
264.27
Form
Crystalline
Melting point
110°
Boiling Point
160-170° dec.
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in acetone and benzene.

Applications

Silicon tetraacetate is used in the preparation of silicon dioxide thin films by a direct photochemical vapor deposition method. It serves as a precursor to prepare silicon complexes with monofunctional bidentate Schiff bases. It is also used as an alternative to silicon hydride and alkoxide for low-temperature silicon dioxide production. Further, it reacts with ethanol in the absence of water to get silica gel and ethyl acetate. In addition, it is employed as a sol-gel precursor.

Notes

Moisture sensitive. Incompatible with water and strong oxidizing agents.

Literature References

Skoda, D.; Styskalik, A.; Moravec, Z.; Bezdicka, P.; Barnes, C. E.; Pinkas, J. Mesoporous titanosilicates by templated non-hydrolytic sol-gel reactions. J. Sol-Gel Sci. Technol. 2015, 74 (3), 810-822.

Cho, D.; Jeong, Y. Facile fabrication of porous silicon nanowires using water-based polyvinyl alcohol/silicon tetraacetate solution. Mater. Lett. 2015, 160, 503-506.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,8498
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2915.29
TSCA
Yes

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