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In manufacture of titanium pigments and metal, as a catalyst in organic syntheses, in iridescent glass, as a smoke screenTitanium(IV) chloride is used to make titanium metal, pigment titanium dioxide and is used in smoke screens. It is involved in the activation of pyrrolidines for better conversion through a modified Bouveault reaction, to the corresponding alpha, alpha -dimethylamines. In organometllic chemistry, it is used to prepare complexes like titanocene dichloride, which is a precursor to Ziegler-Natta catalysts. Tebbes reagent is an aluminum containing derivative of titanocene used for the olefination reactions.
Shaikh, S. F.; Mane, R. S.; Joo, O. S. Spraying distance and titanium chloride surface treatment effects on DSSC performance of electrosprayed SnO2 photoanodes. RSC Adv. 2014, 4 (68), 35919-35927.
Wan, L.; Zhang, D.; Wang, Q.; Chen, Z.; Weng, L. Trans-1, 2-diphenylethylene bridged salicylaldiminato-isoindoline titanium (IV) chloride complexes: Synthesis, characterization and catalytic polymerization. J. Organomet. Chem. 2013, 724, 155-162.
Hazard Statements: H314-H330-H335
Causes severe skin burns and eye damage. Fatal if inhaled. May cause respiratory irritation.
Precautionary Statements: P260-P264b-P271-P280-P284-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant