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17112 Bismuth(III) bromide, 99% (metals basis)

CAS Number
7787-58-8
Synonyms

Stock No. Size Price ($) Quantity Availability
17112-14 25g 63.60
17112-22 100g 206.00
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Bismuth(III) bromide, 99% (metals basis)

MDL
MFCD00014195
EINECS
232-121-1

Chemical Properties

Formula
BiBr3
Formula Weight
448.71
Form
Powder
Melting point
218°
Boiling Point
453°
Density
5.72
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
Decomposes in water.

Applications

It catalyzes the formation of cyclic carbonates.

Notes

Hygroscopic. Store under inert gas. Store in a cool, dry place in tightly closed container. Incompatible with oxidizing agents, acids, water/ moisture, sodium, and potassium.

Literature References

Xin Cong.; Fang Hu.; Ke-Gang Liu.; Qing-Jiang Liao and Zhu-Jun Yao. Chemoselective Deprotection of Cyclic N,O-Aminals Using Catalytic Bismuth(III) Bromide in Acetonitrile.J. Org. Chem.,2005,70,(11), 4514-4516.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2827.59
TSCA
Yes

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