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18202 Silver carbonate on Celite, ≈0.7 mmole Ag2CO3/g reagent

CAS Number
534-16-7
Synonyms

Stock No. Size Price ($) Quantity Availability
18202-W5 15mmol 186.00
18202-W9 75mmol 827.00
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Silver carbonate on Celite, ≈0.7 mmole Ag2CO3/g reagent

MDL
MFCD00003403
EINECS
208-590-3

Chemical Properties

Formula
Ag2CO3/Celite
Form
Powder
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Soluble in water (0.03 mg/ml at 20°C), dilute HNO3, ammonia and ammonium hydroxide. Insoluble in alcohol.

Applications

Silver carbonate is used in production of silver powder. It is used in microelectronics. Silver carbonate is used as a reagent in organic synthesis. It is employed in Fetizon oxidation, silver carbonate on celite acts as an oxidizing agent to form lactones from diols. It is also used in used in Koenigs-Knorr glycosylation. It is also employed to convert alkyl bromides into alcohols.

Notes

Store at room temperature. Keep container tightly closed in a dry and well-ventilated place.

Literature References

Frederic J. Kakis.; Marcel Fetizon.; Nicolas Douchkine.; Michel Golfier.; Philippe Mourgues.; Thierry Prange. Mechanistic studies regarding the oxidation of alcohols by silver carbonate on celite.J. Org. Chem.1974,39(4), 523-533.

GHS Hazard and Precautionary Statements

Hazard Statements: H318-H335-H373

Causes serious eye damage. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P271-P280-P304+P340-P305+P351+P338-P310-P312-P314-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Get medical advice/attention if you feel unwell. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
9
Packing Group
III
Harmonized Tariff Code
3815.12
TSCA
Yes

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