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18641 Silver methanesulfonate

CAS Number
2386-52-9
Synonyms

Stock No. Size Price ($) Quantity Availability
18641-09 10g 102.00
18641-18 50g 494.00
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Silver methanesulfonate

MDL
MFCD00064795
EINECS
219-199-2

Chemical Properties

Formula
CH3AgO3S
Formula Weight
202.97
Form
Powder
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Solubility
Soluble in water, alcohol, ether and benzene. Slightly soluble in toluene, o-chlorotoluene and ethyl disulfide. Insoluble in hexane and methylcyclopentane.

Applications

Silver methanesulfonate is used as a catalyst for heterocyclization reactions. Further, it is used in the synthesis of unsaturated ketones and esters.

Notes

Light sensitive. Incompatible withstrong oxidizing agents.

Literature References

Reinheimer, E. W.; Hodzic, I.; Rath, N. P.; Groeneman, R. H. Varying the extended packing of silver(I) ladder-like coordination polymers by modifying the organic group of various organosulfonate anions. Polyhedron 2015, 98, 105-112.

Hahn, L.; Öz, S.; Wadepohl, H.; Gade, L. H. Highly emissive water-soluble tetraazaperopyrenes as fluorescent markers. Chem. Commun. 2014, 50 (38), 4941-4943.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.29
TSCA
Yes
RTECS
PB2685000

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