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18811 Nickel(II) 2,4-pentanedionate, 95%

CAS Number
3264-82-2
Synonyms
Bis(acetylacetonato)nickel(II)
Nickel(II) acetylacetonate

Stock No. Size Price ($) Quantity Availability
18811-06 5g 24.60
18811-14 25g 39.50
18811-22 100g 94.40
18811-36 500g 299.00
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Nickel(II) 2,4-pentanedionate, 95%

MDL
MFCD00000024
EINECS
221-875-7

Chemical Properties

Formula
C10H14NiO4
Formula Weight
256.91
Form
Powder
Melting point
ca 230° dec.
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in water, alcohol, toluene.

Applications

Catalyst and U.V. stabilizer.Nickel(II) 2,4-pentanedionate is used as a precursor to nickel bis(cyclooctadiene) catalyst. It is also used in the deposition of nickel(II) oxide thin film by sol-gel techniques on conductive glass substrates. Further, it is used in organic synthesis to produce organometals. It is associated with dimethylgold(III) acetylacetonate is used in gold on nickel plating.

Notes

Hygroscopic. Incompatible with strong oxidizing agents and water.

Literature References

Niu, W.; Li, L.; Liu, X.; Zhou, W.; Li, W.; Lu, J.; Chen, S. One-pot synthesis of graphene/carbon nanospheres/graphene sandwich supported Pt3 Ni nanoparticles with enhanced electrocatalytic activity in methanol oxidation. Int. J. Hydrogen Energy 2015, 40 (15), 5106-5114.

Wang, Y.; Chen, Y.; Nan, C.; Li, L.; Wang, D.; Peng, Q.; Li, Y. Phase-transfer interface promoted corrosion from PtNi10 nanoctahedra to Pt4Ni nanoframes. Nano Res. 2015, 8 (1), 140-155.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H317-H334-H350i-H500

Harmful if swallowed. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause cancer by inhalation. May form combustible dust concentrations in air

Precautionary Statements: P201-P202-P261-P264b-P270-P272-P280g-P281-P285-P301+P312-P302+P352-P304+P341-P308+P313-P330-P333+P313-P342+P311-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. If skin irritation or rash occurs: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,6500
Beilstein
4157970
Harmonized Tariff Code
2914.19
TSCA
Yes
RTECS
SA2100000

Recommended

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  • 12537

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  • 33278

    tert-Butyl alcohol, ACS, 99+%

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