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18865 Cesium propionate, complex with propionic acid

CAS Number
38869-24-8
Synonyms

Stock No. Size Price ($) Quantity Availability
18865-04 2g 34.00
18865-09 10g 120.00
18865-18 50g 477.00
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Cesium propionate, complex with propionic acid

MDL
MFCD00014025

Chemical Properties

Formula
CsO2CC2H5•CH3CH2CO2H
Formula Weight
280.06
Form
Crystalline
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Soluble in dimethyl formamide, dimethyl sulfoxide.

Applications

Cesium propionate is used as an pharmaceutical intermediate. It is as an epoxide cleavage and inversion reagent.

Notes

Desiccate at room temperature. Incompatible with oxidizing agents. Hygroscopic.

Literature References

David O Arbelo.; José A Prieto. Cesium propionate as an epoxide cleavage and inversion reagent. Tetrahedron Lett. 2002, 43 (22),4111-4114.

Wim H. Kruizinga.; Bert Strijtveen.; Richard M. Kellogg. Cesium carboxylates in dimethyl formamide. Reagents for introduction of hydroxyl groups by nucleophilic substitution and for inversion of configuration of secondary alcohols. J. Org. Chem. 1981, 46 (21),4321-4323.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2915.50
TSCA
No

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