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21162 Palladium, 5% on barium sulfate powder, unreduced

CAS Number
Synonyms

Stock No. Size Price ($) Quantity Availability
21162-09 10g 75.40
21162-18 50g 311.00
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Palladium, 5% on barium sulfate powder, unreduced

MDL
MFCD03613605

Chemical Properties

Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Hydrodehalogenation, Rosenmund reduction, asymetric hydrogenationPalladium, 5% on barium sulfate powder is used as a catalyst for hydrogenation reaction. It is also used to catalyze the hydrogenation of acyl chlorides to aldehydes. Further, it is used in the Rosenmund reduction.

Notes

Incompatible with oxidizing agents.

Literature References

Miller, C. M.; Benneche, T.; Tius, M. A. First total synthesis of the marine natural products clavulolactones II and III. Org. Biomol. Chem. 2015, 13 (13), 4051-4058.

Suryavanshi, V. J.; Pawar, R. R.; Anuse, M. A.; Mulik, G. N. 2-Octylaminopyridine assisted solvent extraction system for selective separation of palladium(II) ion-pair complex from synthetic mixtures and real samples. Anal. Methods 2015, 7 (6), 2497-2504.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H332

Harmful if swallowed. Harmful if inhaled.

Precautionary Statements: P264b-P270-P271-P301+P312-P304+P340-P312-P330-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
3815.12
TSCA
Yes

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