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22979 Titanium(IV) chloride, 99.99% (metals basis)

CAS Number
7550-45-0
Synonyms
Titanium tetrachloride
Titanic chloride

Stock No. Size Price ($) Quantity Availability
22979-88 2.5g 45.50
22979-14 25g 58.20
22979-22 100g 171.00
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Titanium(IV) chloride, 99.99% (metals basis)

MDL
MFCD00011267
EINECS
231-441-9

Chemical Properties

Formula
Cl4Ti
Formula Weight
189.69
Form
Liquid
Melting point
-25°
Boiling Point
136-137°
Density
1.726
Refractive Index
1.61
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Miscible with ethanol, hydrochloric acid and organic solvents.

Applications

Titanium(IV) chloride is used to make titanium metal, pigment titanium dioxide and is used in smoke screens. It is involved in the activation of pyrrolidines for better conversion through a modified Bouveault reaction, to the corresponding alpha, alpha -dimethylamines. In organometllic chemistry, it is used to prepare complexes like titanocene dichloride, which is a precursor to Ziegler-Natta catalysts. Tebbe’s reagent is an aluminum containing derivative of titanocene used for the olefination reactions.

Notes

Moisture sensitive. Incompatible with ammonia, amines, alcohols, potassium, chemically active metals, strong oxidizing agents and water.

Literature References

Romero, L.; Sobrido, A. B. J.; McMillian, P. F.; Binions, R. On titanium dioxide thin films growth from the direct current electric field assisted chemical vapour deposition of titanium (IV) chloride in toluene. Thin Solid Films 2015, 584, 320-325.

Pei, S.; Xue, C.; Hai, L.; Wu, Y. Synthesis of beta-enaminodicarbonyl derivatives in the titanium (iv) chloride-promoted reactions of beta-dicarbonyl compounds with nitriles. RSC Adv. 2014, 4 (72), 38055-38058.

GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260u-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Merck
14,9478
Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2827.39
TSCA
Yes
RTECS
XR1925000

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