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22979 Titanium(IV) chloride, 99.99% (metals basis)

CAS Number
7550-45-0
Synonyms
Titanium tetrachloride
Titanic chloride

Stock No. Size Price ($) Quantity Availability
22979-88 2.5g 46.90
22979-14 25g 60.00
22979-22 100g 176.00
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Titanium(IV) chloride, 99.99% (metals basis)

MDL
MFCD00011267
EINECS
231-441-9

Chemical Properties

Formula
Cl4Ti
Formula Weight
189.69
Form
Liquid
Melting point
-25°
Boiling Point
136-137°
Density
1.726
Refractive Index
1.61
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Miscible with ethanol, hydrochloric acid and organic solvents.

Applications

Titanium(IV) chloride is used to make titanium metal, pigment titanium dioxide and is used in smoke screens. It is involved in the activation of pyrrolidines for better conversion through a modified Bouveault reaction, to the corresponding alpha, alpha -dimethylamines. In organometllic chemistry, it is used to prepare complexes like titanocene dichloride, which is a precursor to Ziegler-Natta catalysts. Tebbe’s reagent is an aluminum containing derivative of titanocene used for the olefination reactions.

Notes

Moisture sensitive. Incompatible with ammonia, amines, alcohols, potassium, chemically active metals, strong oxidizing agents and water.

Literature References

Romero, L.; Sobrido, A. B. J.; McMillian, P. F.; Binions, R. On titanium dioxide thin films growth from the direct current electric field assisted chemical vapour deposition of titanium (IV) chloride in toluene. Thin Solid Films 2015, 584, 320-325.

Pei, S.; Xue, C.; Hai, L.; Wu, Y. Synthesis of beta-enaminodicarbonyl derivatives in the titanium (iv) chloride-promoted reactions of beta-dicarbonyl compounds with nitriles. RSC Adv. 2014, 4 (72), 38055-38058.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H330-H335

Causes severe skin burns and eye damage. Fatal if inhaled. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P284-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,9478
Hazard Class
6.1
Packing Group
I
Harmonized Tariff Code
2827.39
TSCA
Yes
RTECS
XR1925000

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