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22989 Zirconium(IV) n-propoxide, 70% w/w in n-propanol

CAS Number
23519-77-9
Synonyms
Tetra-n-propyl zirconate

Stock No. Size Price ($) Quantity Availability
22989-18 50g 20.60
22989-36 500g 93.20
22989-A3 2kg 292.00
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Zirconium(IV) n-propoxide, 70% w/w in n-propanol

MDL
MFCD00015307
EINECS
245-711-9

Chemical Properties

Formula
Zr[O(CH2)2CH3]4
Formula Weight
327.56
Form
Liquid
Flash Point
28°(83°F)
Density
1.044
Refractive Index
1.4510
Storage & Sensitivity
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Hydrolyzes in waterImmiscible with water.

Applications

Zirconium(IV) n-propoxide is used as a precursor in the production of zirconia. It is also used to study the thermophysical properties like thermal conductivity and thermal effusivity of hybrid films and thereby adjusting optic properties of the films.

Notes

Moisture sensitive. Store in a cool place. Incompatible with strong oxidizing agents. Hydrolyzes in water.

Literature References

Ghelich, R.; Aghdam, R. M.; Torknik, F. S.; Jahannama, M. R.; Keyanpour-Rad, M. Carbothermal reduction synthesis of ZrB2 nanofibers via pre-oxidized electrospun zirconium n-propoxide. Ceram. Int. 2015, 41 (5), 6905-6911.

Bahrami, M.; Borhani, G. H.; Bakhshi, S. R.; Ghasemi, A. Preparation and evaluation of corrosion behavior of GPTMS-TEOS hybrid coatings containing Zr and Ce on aluminum alloy 6061-T6. J. Sol-Gel Sci. Technol. 2015, 76 (3), 552-561.

GHS Hazard and Precautionary Statements

Hazard Statements: H226-H318-H335-H336

Flammable liquid and vapour. Causes serious eye damage. May cause respiratory irritation. May cause drowsiness or dizziness.

Precautionary Statements: P210-P233-P235-P240-P241-P242-P243-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Keep cool. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2905.19
TSCA
Yes

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