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30167 Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

CAS Number
15629-92-2
Synonyms
1,3-Bis(diphenylphosphino)propane nickel(II) chloride

Stock No. Size Price ($) Quantity Availability
30167-04 2g 39.50
30167-09 10g 140.00
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Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

MDL
MFCD00015318

Chemical Properties

Formula
C27H26Cl2NiP2
Formula Weight
542.03
Form
Powder
Melting point
213° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

Notes

Moisture sensitive. Incompatible withstrong oxidizing agents.

Literature References

Li, J.; Shi, W.; Zhang, J.; Nurulla, I. p-benzoquinone diimines and thiophene based alternating copolymers: organometallic catalyzed syntheses and elementary characterization. J. Polym. Res. 2012, 19 (2), 1-9.

Yamamoto, T.; Nurulla, I.; Ushiro, A. Organometallic C-N coupling between N, N'-dichloro-p-benzoquinone diimine and Grignard reagents and its application to synthesis of polyanilines. Tetrahedron Lett. 2001, 42 (49), 8653-8656.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H317-H319-H334-H335-H350

Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. May cause cancer.

Precautionary Statements: P201-P202-P261-P264b-P271-P272-P280-P281-P285-P302+P352-P304+P340-P305+P351+P338-P308+P313-P333+P313-P337+P313-P342+P311-P362-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: If eye irritation persists: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.39
TSCA
No

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