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Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.
Li, J.; Shi, W.; Zhang, J.; Nurulla, I. p-benzoquinone diimines and thiophene based alternating copolymers: organometallic catalyzed syntheses and elementary characterization. J. Polym. Res. 2012, 19 (2), 1-9.
Yamamoto, T.; Nurulla, I.; Ushiro, A. Organometallic C-N coupling between N, N'-dichloro-p-benzoquinone diimine and Grignard reagents and its application to synthesis of polyanilines. Tetrahedron Lett. 2001, 42 (49), 8653-8656.
Hazard Statements: H315-H319-H317-H351-H335
Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation.
Precautionary Statements: P201-P261-P280-P305+P351+P338-P405-P501a
Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.