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30167 Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

CAS Number
15629-92-2
Synonyms
1,3-Bis(diphenylphosphino)propane nickel(II) chloride

Stock No. Size Price ($) Quantity Availability
30167-04 2g 38.20
30167-09 10g 137.00
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Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)

MDL
MFCD00015318

Chemical Properties

Formula
C27H26Cl2NiP2
Formula Weight
542.03
Form
Powder
Melting point
213° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II) is used as an effective catalyst for Kumada coupling and Suzuki reactions. It also catalyzes other reactions to convert enol ethers, dithioacetals and vinyl sulfides to olefins. Further, it is used as a catalyst for preparation of block-copolythiophenes and solid state metathesis polycondensation.

Notes

Moisture sensitive. Incompatible withstrong oxidizing agents.

Literature References

Li, J.; Shi, W.; Zhang, J.; Nurulla, I. p-benzoquinone diimines and thiophene based alternating copolymers: organometallic catalyzed syntheses and elementary characterization. J. Polym. Res. 2012, 19 (2), 1-9.

Yamamoto, T.; Nurulla, I.; Ushiro, A. Organometallic C-N coupling between N, N'-dichloro-p-benzoquinone diimine and Grignard reagents and its application to synthesis of polyanilines. Tetrahedron Lett. 2001, 42 (49), 8653-8656.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H317-H351-H335

Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing cancer. May cause respiratory irritation.

Precautionary Statements: P201-P261-P280-P305+P351+P338-P405-P501a

Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Harmonized Tariff Code
2931.39
TSCA
No

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