Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

30303 Allyldiphenylphosphine, 96%

CAS Number
2741-38-0
Synonyms

This item cannot be ordered online at this time. Please try again later, or request a bulk quote.

Add to Quote Request

Allyldiphenylphosphine, 96%

MDL
MFCD00014954

Chemical Properties

Formula
C15H15P
Formula Weight
226.25
Form
Liquid
Boiling Point
194-200°/15mm
Flash Point
>110°(230°F)
Density
1.049
Refractive Index
1.6190
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Soluble in most organic solvents. Insoluble in water.

Applications

Allyldiphenylphosphine is used as a cocatalyst in palladium catalyzed hydrocarboxylation reactions, cocatalyst in Palladium catalyzed cross-coupling reactions, ligand for hydroformylation catalysts, ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions, catalyst precursor for alkene hydroboration.

Notes

Store under inert atmosphere. Keep container tightly closed. Store away from oxidizing agents.

Literature References

Yoshihiko Ikeda.; Junzo Ukai.; Nobuo Ikeda.; Hisashi Yamamoto. Stereoselective synthesis of (Full-size image (<1 K))- and (Full-size image (<1 K))-1,3-alkadienes from aldehydes using organotitanium and lithium reagents. Tetrahedron. 1987, 43, (4), 723-730.

Nizamettin Gul.; John H. Nelson. Halide-Bridged Palladium(II) Dimers of Orthometalated (S)-(+)-N,N-Dimethyl-α-methylbenzylamine and (S)-(+)-N,N-Dimethyl[1-(2-naphthyl)ethyl]amine:? Solution and Solid-State Structures and Reactions with 3,4-Dimethyl-1-phenylphosphole and Allyldiphenylphosphine. Organometallics. 2000, 19, (1), 91-104.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P280a-P301+P310a-P305+P351+P338-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

  • A12882

    Cerium(IV) ammonium nitrate, 98+%
  • H25887

    Chlorobis(4-methoxyphenyl)phosphine, 98+%
  • H25888

    Chlorobis[4-(trifluoromethyl)phenyl]phosphine, 97%
  • H25889

    Chlorodi(p-tolyl)phosphine, 95%
  • 12391

    Triethylamine, 99+%

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware