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30386 Tricyclohexylphosphine, 96%

CAS Number

Stock No. Size Price ($) Quantity Availability
30386-03 1g 21.90
30386-06 5g 67.00
30386-14 25g 301.00
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Tricyclohexylphosphine, 96%


Chemical Properties

Formula Weight
Melting point
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Soluble in most organic solvents. Insoluble in water.


Tricyclohexylphosphine is used as a ligand in organometallic chemistry. As a reagent, it is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs’catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.


Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

Bowden, A.; Lees, A. M.; Platt, A. W. Inner and outer sphere coordination of tricyclohexylphosphine oxide with lanthanide bromides. Polyhedron 2015, 91, 110-119.

Gololobov, Y. G.; Krasnova, I. Y.; Barabanov, S. V.; Fedyanin, I. V.; Andronati, S. A.; Pavlovskii, V. I. The unexpected formation of ?-ylide in the reaction of 3-azido 1, 4-benzodiazepine with tricyclohexylphosphine. Russ. Chem. Bull. 2015, 64 (1), 233-236.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code


  • A10112

    1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione, 95%
  • A12007

    Hexa-n-butylditin, 97%
  • A12949

    Triphenylcarbenium tetrafluoroborate, 97%
  • B21428

    1,1-Diphenyl-2-propyn-1-ol, 99%
  • 10173


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