Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

30386 Tricyclohexylphosphine, 96%

CAS Number
2622-14-2
Synonyms

Stock No. Size Price ($) Quantity Availability
30386-03 1g 21.90
30386-06 5g 67.00
30386-14 25g 301.00
Add to Cart Bulk/Specialty Print Quote View Item

Tricyclohexylphosphine, 96%

MDL
MFCD00003853
EINECS
220-069-2

Chemical Properties

Formula
(C6H11)3P
Formula Weight
280.42
Form
Solid
Melting point
76-78°
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Soluble in most organic solvents. Insoluble in water.

Applications

Tricyclohexylphosphine is used as a ligand in organometallic chemistry. As a reagent, it is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs’catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.

Notes

Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Literature References

Bowden, A.; Lees, A. M.; Platt, A. W. Inner and outer sphere coordination of tricyclohexylphosphine oxide with lanthanide bromides. Polyhedron 2015, 91, 110-119.

Gololobov, Y. G.; Krasnova, I. Y.; Barabanov, S. V.; Fedyanin, I. V.; Andronati, S. A.; Pavlovskii, V. I. The unexpected formation of ?-ylide in the reaction of 3-azido 1, 4-benzodiazepine with tricyclohexylphosphine. Russ. Chem. Bull. 2015, 64 (1), 233-236.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.39
TSCA
Yes

Recommended

  • A10112

    1,1,1-Trifluoro-5,5-dimethyl-2,4-hexanedione, 95%
  • A12007

    Hexa-n-butylditin, 97%
  • A12949

    Triphenylcarbenium tetrafluoroborate, 97%
  • B21428

    1,1-Diphenyl-2-propyn-1-ol, 99%
  • 10173

    Tribenzylphosphine

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware