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Phase transfer catalystTetraethylammonium chloride monohydrate is used in the preparation of 2,3,4,6-tetra-O-acetyl-beta-D-glucopyranosyl chloride by reacting with 1,2-O-acetoxonium-3,4,6-tri-O-acetyl-alfaD-glucopyranose perchlorate.
Demertzi, D. K.; Kourkoumelis, N.; Derlat, K.; Michalak, J.; Andreadaki, F. J.; Kostas, I. D. Thiosemicarbazone-derivatised palladium nanoparticles as efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides with phenylboronic acid. Inorg. Chim. Acta 2008, 361 (5), 1562-1565.
Grossini, E.; Molinari, C.; Mary, D. A. S. G.; Uberti, F.; Caimmi, P. P.; Vacca, G. Intracoronary intermedin 1-47 augments cardiac perfusion and function in anesthetized pigs: role of calcitonin receptors and beta-adrenoreceptor-mediated nitric oxide release. J. Appl. Physiol. 2009, 107 (4), 1037-1050.
Hazard Statements: H302-H315-H319-H335
Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant