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31154 Iron(II) bromide, anhydrous, 98% min

CAS Number
7789-46-0
Synonyms

Stock No. Size Price ($) Quantity Availability
31154-06 5g 32.90
31154-14 25g 150.00
31154-22 100g 581.00
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Iron(II) bromide, anhydrous, 98% min

MDL
MFCD00016081
EINECS
232-168-8

Chemical Properties

Formula
Br2Fe
Formula Weight
215.67
Form
Granular
Melting point
684°
Density
4.636
Storage & Sensitivity
Hygroscopic. Air Sensitive. Ambient temperatures.
Solubility
Soluble in water, methanol, ethanol and tetrahydrofuran.

Applications

Iron(II) bromide is used as an intermediate in the synthesis porphryins. It is also used as weak reducing agents. It is used as precursor for the preparation of [(C2H5)4N]2FeBr4 by reacting with tetraethylammonium bromide. It is also involved in the synthesis of iron pyrite nanocrystals and nanocrystalline thin films.

Notes

Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with alkali metals like potassium and sodium, and sodium oxides.

Literature References

Gopalaiah, K.; Chandrudu, S. N. Iron(II) bromide-catalyzed oxidative coupling of benzylamines with ortho-substituted anilines: synthesis of 1, 3-benzazoles. RSC Adv. 2015, 5 (7), 5015-5023.

Bhandari, K. P.; Roland, P. J.; Kinner, T.; Cao, Y.; Choi, H.; Jeong, S.; Ellingson, R. J. Analysis and characterization of iron pyrite nanocrystals and nanocrystalline thin films derived from bromide anion synthesis. J. Mater. Chem. A 2015, 3 (13), 6853-6861.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H314-H318

Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P280-P305+P351+P338-P309-P310a

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor

Other References

Merck
14,4042
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2827.59
TSCA
Yes

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