Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

32583 Dichlorophenylborane, 96%

CAS Number
873-51-8
Synonyms
Phenylboron dichloride

Stock No. Size Price ($) Quantity Availability
32583-03 1g 24.00
32583-06 5g 91.20
32583-14 25g 372.00
Add to Cart Add to Quote Request View Item

Dichlorophenylborane, 96%

MDL
MFCD00013612

Chemical Properties

Formula
C6H5BCl2
Formula Weight
158.83
Form
Liquid
Melting point
Boiling Point
175°
Flash Point
14°(57°F)
Density
1.194
Refractive Index
1.545
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in water (Reacts violently).

Applications

Dichlorophenylborane is widely used as a catalyst in Antiproliferative macrolide and cell migration inhibitor lactimidomycin and in enantioselective synthesis of polypeptide segments using vinylogous Mukaiyama aldol reactions and in enantioselective Diels-Alder cycloadditions after its reaction with allo-threonine derivatives. It is a stereo selective alkylative ring opening of cyclic anhydrides and in cross-metathesis reaction of amino derivatives with olefines.

Notes

Hygroscopic. Store at room temperature.

Literature References

Cheuk Kun Lau.; Marcy Mintz.; Michael A. Bernstein.;Claude Dufresne. Dichlorophenylborane a new reagent for the preparation of 2-phenyl-4H-1,3,2-benzodioxaborins Tetrahedron Letters1993, 34 (35), 5527-5530.

GHS Hazard and Precautionary Statements

Hazard Statements: H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Precautionary Statements: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Beilstein
2243576
Hazard Class
3
Packing Group
II
Harmonized Tariff Code
2931.90
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware