Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

32589 Triphenylborane, 96%

CAS Number
960-71-4
Synonyms
Triphenylboron

Stock No. Size Price ($) Quantity Availability
32589-03 1g 37.00
32589-06 5g 146.00
32589-14 25g 598.00
Add to Cart Add to Quote Request View Item

Triphenylborane, 96%

MDL
MFCD00003007
EINECS
213-504-2

Chemical Properties

Formula
(C6H5)3B
Formula Weight
242.13
Form
Crystalline
Melting point
147°
Boiling Point
208°/14mm
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Soluble in aromatic solvents. Insoluble in water.

Applications

Triphenylborane is used as a precursor in the production of pyridine-triphenylborane complex, which is used as a catalyst for the polymerization of acrylic esters. It is also used in the hydrocyanation of butadiene to adiponitrile. It is involved in the synthesis of 3-phenyl-cyclohexene by reacting with acetic acid cyclohex-2-enyl ester in presence of palladium bis(dibenzylideneacetone) and triphenylphosphine as a catalyst.

Notes

Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Literature References

Kushida, T.; Shuto, A.; Yoshio, M.; Kato, T.; Yamaguchi, S. A Planarized Triphenylborane Mesogen: Discotic Liquid Crystals with Ambipolar Charge-Carrier Transport Properties. Angew. Chem. Int. Ed. 2015, 127 (23), 7026-7029.

Chan, L.; McNally, A.; Toh, Q. Y.; Mendoza, A.; Gaunt, M. J. A counteranion triggered arylation strategy using diaryliodonium fluorides. Chem. Sci. 2015, 6 (2), 1277-1281.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H318

Flammable solid. Causes serious eye damage.

Precautionary Statements: P210-P280a-P240-P241-P305+P351+P338-P310a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor

Other References

Beilstein
1961313
Hazard Class
4.1
Packing Group
III
Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
ED2367500

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware