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Triphenylborane is used as a precursor in the production of pyridine-triphenylborane complex, which is used as a catalyst for the polymerization of acrylic esters. It is also used in the hydrocyanation of butadiene to adiponitrile. It is involved in the synthesis of 3-phenyl-cyclohexene by reacting with acetic acid cyclohex-2-enyl ester in presence of palladium bis(dibenzylideneacetone) and triphenylphosphine as a catalyst.
Kushida, T.; Shuto, A.; Yoshio, M.; Kato, T.; Yamaguchi, S. A Planarized Triphenylborane Mesogen: Discotic Liquid Crystals with Ambipolar Charge-Carrier Transport Properties. Angew. Chem. Int. Ed. 2015, 127 (23), 7026-7029.
Chan, L.; McNally, A.; Toh, Q. Y.; Mendoza, A.; Gaunt, M. J. A counteranion triggered arylation strategy using diaryliodonium fluorides. Chem. Sci. 2015, 6 (2), 1277-1281.
Hazard Statements: H228-H318
Flammable solid. Causes serious eye damage.
Precautionary Statements: P210-P280a-P240-P241-P305+P351+P338-P310a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor