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32635 Benzyl azide, 94%

CAS Number
622-79-7
Synonyms
Triazotoluene

Stock No. Size Price ($) Quantity Availability
32635-04 2g 44.90
32635-09 10g 137.00
32635-18 50g 539.00
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Benzyl azide, 94%

MDL
MFCD00013836

Chemical Properties

Formula
C6H5CH2N3
Formula Weight
133.15
Form
Liquid
Boiling Point
82-85°/16mm
Flash Point
43°(110°F)
Density
1.065
Refractive Index
1.5341
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in waterMiscible with ethanol and diethyl ether. Immiscible with water.

Applications

Benzyl azide is used in the synthesis of 1,2,3-triazole derivatives. It serves as a reagent used to introduce a PhCH2N group into a molecule.

Notes

Store in a cool place. Light sensitive. Incompatible with alkali metals, strong oxidizing agents, amines, magnesium, strong acids, vinyl compounds, reducing agents and strong bases.

Literature References

Pinto, R. M.; Guerra, M.; Costa, M. L.; Dias, A. A. Reply to “Comment on ‘The Mechanism of Pyrolysis of Benzyl Azide: Spectroscopic Evidence for Benzemethanimine Formation’”. J. Phys. Chem. A 2015, 119 (29), 8258-8259.

Thevenet, N.; de la Sovera, V.; Vila, M. A.; Veiga, N.; Gonzalez, D.; Seoane, G.; Carrera, I. Double [3, 3]-Sigmatropic Rearrangement in the Enzymatic Dioxygenation of Benzyl Azide: Preparation of Novel Synthetically Valuable Azido-diols. Org. Lett. 2015, 17 (3), 684-687.

GHS Hazard and Precautionary Statements

Hazard Statements: H226

Flammable liquid and vapour.

Precautionary Statements: P210-P233-P240-P241-P242-P243-P280-P303+P361+P353-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
3
Packing Group
III
Harmonized Tariff Code
2928.00
TSCA
No
RTECS
XS6650000

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