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As a primary standard for preparing volumetric alkali solutions and as a buffer in pH determinations. Potassium hydrogen phthalate is used as a primary standard for acid- base titrations as well as for calibrating pH meters. It acts as a buffer in pH determination. It finds application as a useful standard for total organic carbon testing.
Kahr, B.; Bullard, T.; Kurimoto, M.; Yoreo, J. J. Complex organic guests in simple crystals: potassium hydrogen phthalate as case study. Cryst. Res. Technol. 2013, 48 (10), 849-863.
Sudhahar, S.; Kumar, M. K.; Jayaramakrishnan, V.; Muralidharan, R.; Kumar, R. M. Effect of Sm+ Rare Earth Ion on the Structural, Thermal, Mechanical and Optical Properties of Potassium Hydrogen Phthalate Single Crystals. J. Mater. Sci. Technol. 2014, 30 (1), 13-18.