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35479 Lithium nitride, 99.4% (metals basis)

CAS Number
26134-62-3
Synonyms

Stock No. Size Price ($) Quantity Availability
35479-09 10g 57.90
35479-18 50g 225.00
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Lithium nitride, 99.4% (metals basis)

MDL
MFCD00016186
EINECS
247-475-2

Chemical Properties

Formula
Li3N
Formula Weight
34.82
Form
-60 Mesh Powder
Melting point
845°
Density
1.30
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Insoluble in organic solvents.

Applications

Lithium nitride is used in metallurgy and chemical synthesis. It is also used to store hydrogen and acts as a source of the nitride ion. It is involved in the preparation of lithium hydride and lithium amide as well as a reducing agent.

Notes

Moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents, acids, water, copper, carbon tetrachloride and silicon tetrafluoride.

Literature References

Li, Z.; Zhang, J.; Wang, S.; Jiang, L.; Latroche, M.; Du, J.; Cuevas, F. Mechanochemistry of lithium nitride under hydrogen gas. Phys. Chem. Chem. Phys. 2015, 17 (34), 21927-21934.

Goshome, K.; Miyaoka, H.; Yamamoto, H.; Ichikawa, T.; Ichikawa, T.; Kojima, Y. Ammonia Synthesis via Non-Equilibrium Reaction of Lithium Nitride in Hydrogen Flow Condition. Mater. Trans. 2015, 56 (3), 410-414.

GHS Hazard and Precautionary Statements

Hazard Statements: H250-H260-H314-H335

Catches fire spontaneously if exposed to air. In contact with water releases flammable gases which may ignite spontaneously. Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P210-P222-P223-P231+P232-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P335+P334-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air. Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
4.3
Packing Group
I
Harmonized Tariff Code
2850.00
TSCA
Yes

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