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35481 Copper(II) acetate monohydrate, 99.9% (metals basis)

CAS Number
6046-93-1
Synonyms

Stock No. Size Price ($) Quantity Availability
35481-06 5g 61.80
35481-14 25g 232.00
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Copper(II) acetate monohydrate, 99.9% (metals basis)

MDL
MFCD00149570
EINECS
205-553-3

Chemical Properties

Formula
C4H6CuO4•H2O
Formula Weight
199.65 (181.64anhy)
Form
-4 Mesh
Melting point
115°
Density
1.882
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water (72 mg/ml at 20°C), alcohol, ether (slightly), and glycerin (slightly).

Applications

Copper(II) acetate monohydrate is used in formation of Cu chelates of ß-dicarbonyl compounds as a means of purification and in the eglinton (modified glaser) coupling of terminal alkynes. It is also used as a catalyst for the michael reaction giving increased yields and absence of side-reactions. It Promotes ullmann-type C-O and C-N coupling reactions of arylboronic acids with phenols, amines and various other nitrogen derivatives. It is also used in biochemical applications such as DNA extraction.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is non-combustible. Incompatible with oxidizing agents.

Literature References

Fang Huang.; Robert A. Batey. Cross-coupling of organoboronic acids and sulfinate salts using catalytic copper(II) acetate and 1,10-phenanthroline: synthesis of aryl and alkenylsulfones.Tetrahedron.2007,63(32), 7667-7672.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H314-H335-H373

Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,2624
Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2915.29
TSCA
Yes
RTECS
AG3500000

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