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35680 Bismuth(III) chloride, ultra dry, 99.997+% (metals basis)

CAS Number
7787-60-2
Synonyms

Stock No. Size Price ($) Quantity Availability
35680-06 5g 34.90
35680-14 25g 147.00
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Bismuth(III) chloride, ultra dry, 99.997+% (metals basis)

MDL
MFCD00003461
EINECS
232-123-2

Chemical Properties

Formula
BiCl3
Formula Weight
315.34
Form
Powder, Ampouled under argon
Melting point
230-232°
Boiling Point
ca 430° subl.
Density
4.75
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubility
It is soluble in methanol, diethyl ether, acetone.

Applications

Bismuth chloride is used as a catalyst in organic synthesis. In particular, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. The addition of other metal iodides increases its catalytic activity.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from strong oxidizing agents.

Literature References

B Garrigues.; F Gonzaga.; H Robert. Bismuth (III) chloride or triflate-catalyzed dienophilic activity of α-ethylenic aldehydes and ketones. J. Org. Chem. 1997, 62, (14), 4880-4882.

H Robert.; B Garrigues.;J Dubac . The carbonyl-Diels-Alder reaction catalyzed by bismuth (III) chloride. Tetrahedron Letters. . 1997, 39, (10), 1161-1164.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,1262
Harmonized Tariff Code
2827.39
TSCA
Yes
RTECS
EB2690000

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