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35697 Gallium(III) bromide, ultra dry, 99.998% (metals basis)

CAS Number
13450-88-9
Synonyms

Stock No. Size Price ($) Quantity Availability
35697-03 1g 81.10
35697-06 5g 223.00
35697-14 25g 605.00
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Gallium(III) bromide, ultra dry, 99.998% (metals basis)

MDL
MFCD00016100
EINECS
236-609-5

Chemical Properties

Formula
GaBr3
Formula Weight
309.45
Form
Crystalline, Ampouled under argon
Melting point
122°
Boiling Point
279°
Density
3.69
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
Soluble in water.

Applications

Gallium bromide is used as a catalyst in the alkylation of aromatic compounds by alkyl bromides.

Notes

Moisture sensitive. Incompatible with strong oxidizing agents.

Literature References

Novikov, R. A.; Potapov, K. V.; Chistikov, D. N.; Tarasova, A. V.; Grigoriev, M. S.; Timofeev, V. P.; Tomilov, Y. V. Synthesis and Structures of Cyclopropanedicarboxylate Gallium Complexes. Organometallics 2015, 34 (17), 4238-4250.

Hullaert, J.; Laplace, D. R.; Winne, J. M. A Three-Step Synthesis of the Guaianolide Ring System. Eur. J. Org. Chem. 2014, 2014 (15), 3097-3100.

GHS Hazard and Precautionary Statements

Hazard Statements: H314

Causes severe skin burns and eye damage.

Precautionary Statements: P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2827.59
TSCA
Yes

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