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36213 Ammonium vanadium oxide, ACS, 99.0% min

CAS Number
7803-55-6
Synonyms
Ammonium metavanadate
Ammonium vanadate

Stock No. Size Price ($) Quantity Availability
36213-18 50g 39.60
36213-30 250g 133.00
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Ammonium vanadium oxide, ACS, 99.0% min

MDL
MFCD00011430
EINECS
232-261-3

Chemical Properties

Formula
NH4VO3
Formula Weight
116.98
Form
Powder
Melting point
200° dec.
Density
2.33
Storage & Sensitivity
Ambient temperatures.
Solubility
Slightly soluble in water. Soluble in dilute ammoniaSlightly soluble in water. Soluble in dilute ammonia and diethanolamine. Insoluble in ether and alcohol.

Grade Specifications

Maximum level of impurities: Solubility in ammonium hydroxide P.T., CO3 P.T. (about 0.3%), Cl 0.2%, SO4 0.05%

Applications

Ammonium vanadium oxide is used as a catalyst in organic synthesis, and as an analytical reagent in laboratories. It is employed in the preparation of vanadate. It acts as a sensor for the determination of N-acetyltransferase activity in humans. Further it finds use in dyes, varnishes, indelible inks, drier for paints, and in photography. With copper carbonate, it has been shown to enhance the catalytic activities. Ammonium metavanadate is an environmental-friendly catalyst to prepare alpha-hydroxyphosphonate derivatives in high yield through the reaction of aryl/heteroaryl aldehydes with triethylphosphonate derivatives.

Notes

It is hygroscopic in nature. It is incompatible with strong oxidizing agents and strong acids.

Literature References

Niralwad, K. S.; Shingate, B. B.; Shingare, M. S. Microwave Assisted One-pot Synthesis of Octahydroquinazolinone Derivatives using Ammonium metavanadate under Solvent-free condition. Tetrahedron Lett. 2010, 51 (28), 3616-3618.

Bernal, H. G.; Caero, L. C.; Alejandre, A. G. Liquid Phase Oxidation of Dibenzothiophene with Alumina-Supported Vanadium Oxide Catalysts: An Alternative to Deep Desulfurization Of Diesel. Catal. Today 2009, 142 (3-4), 227-233.

Sonar, S. S.; Kategaonkar, A. H.; Ware, M. N.; Gill, C. H.; Shingate, B. B.; Shingare, M. S. Ammonium metavanadate: an effective catalyst for synthesis of alpha-hydroxyphosphonates. ARKIVOC 2009, 2, 138-148.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H319-H332-H361d-H372

Toxic if swallowed. Causes serious eye irritation. Harmful if inhaled. Suspected of damaging the unborn child. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P201-P202-P260-P264b-P270-P271-P280i-P281-P301+P310-P304+P340-P305+P351+P338-P308+P313-P330-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear eye/face protection. Use personal protective equipment as required. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Rinse mouth. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,568
Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2841.90
TSCA
Yes

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