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38367 Cerium(III) ammonium nitrate tetrahydrate, Reagent Grade

CAS Number
13083-04-0
Synonyms
Ammonium cerium(III) nitrate

Stock No. Size Price ($) Quantity Availability
38367-22 100g 41.10
38367-36 500g 135.00
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Cerium(III) ammonium nitrate tetrahydrate, Reagent Grade

MDL
MFCD00210608

Chemical Properties

Formula
H8CeN7O15•4H2O
Formula Weight
558.28 (486.22anhy)
Form
Crystalline
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

A useful oxidant for organic synthesis. This chemical is also useful for the synthesis of quinoxaline derivatives which are useful as DNA cleaving agents, dyes, and organic semiconductors. Used to release organic ligands from metal carbonyls. Whereby the metal is oxidized, Carbon monoxide is produced, and the organic ligand is released.

Notes

Store in cool, dry conditions in well sealed containers. Do not store with organic materials. Store away from reducing agent and metal powders.

Literature References

Ken-ichi Itoh; C.Akira Horiuchi. Formation of isoxazole derivatives via nitrile oxide using ammonium cerium nitrate (CAN): a novel one-pot synthesis of 3-acetyl- and 3-benzoylisoxazole derivatives. Tetrahedron, 2004, 60 (7), 1671-1681.

C. Akira Horiuchi, Hirotada Fukunishi, Mika Kajita, Akihisa Yamaguchi, Hiroshi Kiyomiya, Shinji Kiji. New Oxidative Aromatization of α,β-Unsaturated Cyclohexenones with Iodine-Cerium(IV) Ammonium Nitrate in Alcohol. Chemistry Letters, 1991, 20 (11), 1921-1924.

GHS Hazard and Precautionary Statements

Hazard Statements: H272-H315-H319

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation.

Precautionary Statements: P210-P220-P221-P264b-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
5.1
Packing Group
III
Harmonized Tariff Code
2846.10
TSCA
Yes

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