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A useful oxidant for organic synthesis. This chemical is also useful for the synthesis of quinoxaline derivatives which are useful as DNA cleaving agents, dyes, and organic semiconductors. Used to release organic ligands from metal carbonyls. Whereby the metal is oxidized, Carbon monoxide is produced, and the organic ligand is released.
Ken-ichi Itoh; C.Akira Horiuchi. Formation of isoxazole derivatives via nitrile oxide using ammonium cerium nitrate (CAN): a novel one-pot synthesis of 3-acetyl- and 3-benzoylisoxazole derivatives. Tetrahedron, 2004, 60 (7), 1671-1681.
C. Akira Horiuchi, Hirotada Fukunishi, Mika Kajita, Akihisa Yamaguchi, Hiroshi Kiyomiya, Shinji Kiji. New Oxidative Aromatization of α,β-Unsaturated Cyclohexenones with Iodine-Cerium(IV) Ammonium Nitrate in Alcohol. Chemistry Letters, 1991, 20 (11), 1921-1924.
Hazard Statements: H272-H315-H319
May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation.
Precautionary Statements: P210-P220-P221-P264b-P280-P302+P352-P305+P351+P338-P332+P313-P362-P370+P378q-P501c
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant