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39288 Bis(ethylene)(2,4-pentanedionato)rhodium(I), Rh 39.9% min

CAS Number
12082-47-2
Synonyms
(Acetylacetonato)bis(ethylene)rhodium(I)

Stock No. Size Price ($) Quantity Availability
39288-MD 250mg 132.00
39288-03 1g 423.00
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Bis(ethylene)(2,4-pentanedionato)rhodium(I), Rh 39.9% min

MDL
MFCD00015354
EINECS
235-147-1

Chemical Properties

Formula
C9H15O2Rh
Formula Weight
258.13
Form
Crystalline
Storage & Sensitivity
Air Sensitive. Ambient temperatures.
Solubility
Soluble in dichloromethane, chloroform

Applications

It acts as a hydrogenation precursor. It is also used as intermediates which acts as catalyst such as in olefin hydroformylation.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature: 2 - 8°C Handle and store under inert gas.

Literature References

Bjoern. Aakermark; Julius. Glaser; Lars; Oehrstroem; Krister. Zetterberg. Alkene exchange kinetics in bis(.eta.2-alkene)(2,4-pentanedionato)rhodium(I) investigated by NMR spectroscopy. Organometallics. 1991, 10 (3), 733-736.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
No

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