Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

39295 Dicarbonyl(2,4-pentanedionato)rhodium(I), 97%

CAS Number
14874-82-9
Synonyms
(Acetylacetonato)dicarbonylrhodium(I)
Acetylacetonatorhodium(I) dicarbonyl

Stock No. Size Price ($) Quantity Availability
39295-MD 250mg 79.90
39295-03 1g 316.00
39295-06 5g 1153.00
Add to Cart Bulk/Specialty Print Quote View Item

Dicarbonyl(2,4-pentanedionato)rhodium(I), 97%

MDL
MFCD00009884
EINECS
238-947-9

Chemical Properties

Formula
C7H7RhO4
Formula Weight
258.04
Form
Crystalline
Melting point
144-147° subl.
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in acetone

Applications

(Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction.

Notes

Store in a cool, dry place in a tightly sealed container. Air and moisture stable.

Literature References

Martin C?apka; Marie Czakoova; Wlodzimierz Urbaniak; Ulrich Schubert. Hydrogenation and hydrosilylation activity of homogeneous and immobilized dicarbonyl(2,4-pentanedionato)rhodium complexes. J. Mol. Catal. 1992, 74 (1-3), 335-344.

GHS Hazard and Precautionary Statements

Hazard Statements: H228-H301-H317-H319

Flammable solid. Toxic if swallowed. May cause an allergic skin reaction. Causes serious eye irritation.

Precautionary Statements: P210-P240-P241-P261-P264b-P270-P272-P280-P301+P310-P302+P352-P305+P351+P338-P330-P333+P313-P337+P313-P363-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Wash contaminated clothing before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
III
Harmonized Tariff Code
2843.90
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware