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Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. Mercuric triflate is a very versatile reagent and has been used for several organic catalytic transformations including C-C bond forming cyclizations, alkyne hydrations, heterocycle synthesis and very recently in C-N bond forming reactions. Commonly used as the metal source for Lewis acid catalyzed asymmetric reactions.
Mugio Nishizawa; Hideyuki Takenaka1; Yuji Hayashi1. Mercury(Ii) TriflateAmine Complex-Induced Cyclization Of Geranylgeranyl P-Nitrobenzoate: Synthesis Of Spondian And Labdane Diterpenoids. Chem. Lett. 1983, 12 (9), 1459-1460.
Hazard Statements: H300-H310-H330-H373
Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements: P260-P262-P264b-P270-P271-P280-P284-P301+P310-P302+P350-P304+P340-P310-P314-P330-P361-P363-P501c
Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Gently wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Rinse mouth. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant