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39305 Mercury(II) trifluoromethanesulfonate, 98%

CAS Number
49540-00-3
Synonyms
Mercury(II) triflate

Stock No. Size Price ($) Quantity Availability
39305-03 1g 41.10
39305-06 5g 91.20
39305-14 25g 295.00
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Mercury(II) trifluoromethanesulfonate, 98%

MDL
MFCD00144746

Chemical Properties

Formula
C2F6HgO6S2
Formula Weight
498.72
Form
Powder
Melting point
>350°
Storage & Sensitivity
Moisture Sensitive. Ambient temperatures.
Solubility
It is soluble in H2O and CH3CN, fairly soluble in CH3NO2 and CH2Cl2, insoluble in hexane, ether, and toluene.

Applications

Hg(OTf)2 exhibits remarkable catalytic activity for the hydroxylative cyclization of 1,6-enynes. Mercuric triflate is a very versatile reagent and has been used for several organic catalytic transformations including C-C bond forming cyclizations, alkyne hydrations, heterocycle synthesis and very recently in C-N bond forming reactions. Commonly used as the metal source for Lewis acid catalyzed asymmetric reactions.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture Sensitive.

Literature References

Mugio Nishizawa; Hideyuki Takenaka1; Yuji Hayashi1. Mercury(Ii) Triflate—Amine Complex-Induced Cyclization Of Geranylgeranyl P-Nitrobenzoate: Synthesis Of Spondian And Labdane Diterpenoids. Chem. Lett. 1983, 12 (9), 1459-1460.

GHS Hazard and Precautionary Statements

Hazard Statements: H300-H310-H330-H373

Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P262-P264b-P270-P271-P280-P284-P301+P310-P302+P350-P304+P340-P310-P314-P330-P361-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Wear respiratory protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Gently wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. Rinse mouth. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
6.1
Packing Group
II
Harmonized Tariff Code
2852.10
TSCA
No

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