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39413 Carbonylchlorobis(triphenylphosphine)iridium(I)

CAS Number
14871-41-1
Synonyms
Vaska's catalyst
Chlorocarbonylbis(triphenylphosphine)iridium(I)

Stock No. Size Price ($) Quantity Availability
39413-01 0.25g 55.50
39413-03 1g 178.00
39413-06 5g 800.00
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Carbonylchlorobis(triphenylphosphine)iridium(I)

MDL
MFCD00009590
EINECS
238-941-6

Chemical Properties

Formula
IrCl(CO)[P(C6H5)3]2
Formula Weight
780.27
Form
Crystalline
Melting point
215° dec.
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol

Applications

Carbonylchlorobis(triphenylphosphine)iridium(I) is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs.

Notes

Store away from oxidizing agents in a cool, dry place in a well-sealed container.

Literature References

Peter D. Brotherton.; Colin L. Raston.; Allan H. White.; Stanley Bruce Wild. Crystal structures of mercury(II) chloride and bromide addition complexes of carbonylchlorobis(triphenylphosphine)iridium(I). Peter D. Brotherton, Colin L. Raston, Allan H. White and Stanley Bruce Wild J. Chem. Soc., Dalton Trans. 1976, (18),1799-1802.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H312-H332

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Rinse mouth. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.90
TSCA
Yes

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