Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

39538 Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt hydrate, tech. 85%

CAS Number
63995-70-0
Synonyms
Tris(3-sulfophenyl)phosphine trisodium salt hydrate

Stock No. Size Price ($) Quantity Availability
39538-01 0.25g 122.00
39538-03 1g 392.00
Add to Cart Bulk/Specialty Print Quote View Item

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt hydrate, tech. 85%

MDL
MFCD00145472
EINECS
264-596-6

Chemical Properties

Formula
C18H12Na3O9PS3•xH2O
Formula Weight
568.41(anhy)
Form
Crystalline
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in water.

Applications

Triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt hydrate is useful for the preparation of water-soluble organometal catalysts, which finds application in the hydroformylation of propene. It acts as a Lewis base, which is stronger than triphenylphosphine.

Notes

Incompatible with strong oxidizing agents.

Literature References

Paganelli, S.; Piccolo, O.; Baldi, F.; Gallo, M.; Tassini, R.; Rancan, M.; Armelao, L. A new biogenerated Rh-based catalyst for aqueous biphasic hydroformylation. Catal. Commun. 2015, 71, 32-36.

Liu, L.; Zhao, M.; Wang, Z.; Qin, Y.; Wang, X. Synthesis and biological evaluation of novel technetium-99m-labeled HYNIC-d-glucose as a potential tumor imaging agent. J. Radioanal. Nucl. Chem. 2014, 301 (3), 731-737.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Beilstein
3584807
Harmonized Tariff Code
2931.39
TSCA
No

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware