Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

39558 Bis(cyclopentadienyl)zirconium dichloride, 99%

CAS Number
1291-32-3
Synonyms
Zirconocene dichloride
Dichlorobis(cyclopentadienyl)zirconium

Stock No. Size Price ($) Quantity Availability
39558-03 1g 16.60
39558-06 5g 32.80
39558-14 25g 104.00
39558-22 100g 404.00
Add to Cart Bulk/Specialty Print Quote View Item

Bis(cyclopentadienyl)zirconium dichloride, 99%

MDL
MFCD00003726
EINECS
215-066-8

Chemical Properties

Formula
C10H10Cl2Zr
Formula Weight
292.32
Form
Powder, Packaged under argon
Melting point
242-245°
Boiling Point
124-125°/15mm
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Insoluble in water.

Applications

Zirconocene dichloride can also be used to prepare the Negishi reagent, Cp2Zr(η2-butene) which is used as a source for Cp2Zr in oxidative cyclisation reactions. 

Notes

Store in a cool dry place. Keep away from oxidizing agents. Air and moisture sensitive.

Literature References

M. Lakshmi Kantam.; Khathija Aziz.; Pravin R. Likhar. Bis(cyclopentadienyl) zirconium dichloride catalyzed acetylation of phenols, alcohols and amines. Catal. Commun. 2006, 7 (7), 484-487.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.90
TSCA
Yes
RTECS
ZH7525000

Recommended

Recently Viewed

Chemicals

Life Science

Metals & Materials

Catalysts

Analytical & Labware