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39570 Bis(pentamethylcyclopentadienyl)titanium dichloride

CAS Number
11136-36-0
Synonyms
Decamethyltitanocene dichloride

Stock No. Size Price ($) Quantity Availability
39570-03 1g 123.00
39570-06 5g 588.00
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Bis(pentamethylcyclopentadienyl)titanium dichloride

MDL
MFCD00049153

Chemical Properties

Formula
C20H30Cl2Ti
Formula Weight
389.23
Form
Crystalline solid
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Reacts with water.

Applications

It is used as an intermediate in the synthesis of troticenyl monophosphanes and [2]troticenophanes with C-P and C-Si bridges.

Notes

Air and moisture sensitive. Store away from air, water/moisture, strong bases and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

Literature References

John E. Bercaw, et al. Titanocene as an intermediate in reactions involving molecular hydrogen and nitrogen.J. Am. Chem. Soc.,1972,94(4), 1219-1238.

Alain C. Tagne Kuate, et al.Mono- and Dilithiation of [(η7-C7H7)Ti(η5-C5Me5)] (Pentamethyltroticene) for the Synthesis of Troticenyl Monophosphanes and [2]Troticenophanes with C-P and C-Si Bridges.Organometallics.,2012,31(24), 8544-8555.

GHS Hazard and Precautionary Statements

Hazard Statements: H302+H312+H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2931.90
TSCA
No

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