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40131 Indium(III) trifluoromethanesulfonate, 99% min

CAS Number
128008-30-0
Synonyms
Indium triflate

Stock No. Size Price ($) Quantity Availability
40131-09 10g 120.00
40131-18 50g 518.00
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Indium(III) trifluoromethanesulfonate, 99% min

MDL
MFCD00144478

Chemical Properties

Formula
In(CF3SO3)3
Formula Weight
562.02
Form
Powder
Melting point
dec.
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Slightly soluble in hydrocarbons and diethyl ether. Insoluble in water

Applications

Indium(III) trifluoromethanesulfonate is used as a Lewis acid catalyst in organic synthesis and as a co-catalyst in organometallic catalysis. It is also used as a reactant in the preparation of stable indium bacteriochlorins and decahydroquinoline-type toxins through intramolecular hetero Diels-Alder reactions. Further, it is used in the synthesis of benzoxazoles through cyclocondensations.

Notes

Hygroscopic. Moisture sensitive. Incompatible with strong oxidizing agents.

Literature References

Selvi, T.; Srinivasan, K. Boron Trifluoride-Promoted Indium(III) Triflate-Catalyzed Sequential One-Pot Synthesis of (1, 2Diaryl-2-oxoethyl)malonates from trans-2-Aryl-3-nitrocyclopropane-1,1dicarboxylates and Activated Arenes. Adv. Synth. Catal. 2015, 357 (9), 2111-2118.

Kean, J. R.; Graham, A. E. Indium(III) triflate promoted synthesis of alkyl levulinates from furyl alcohols and furyl aldehydes. Catal. Commun. 2015, 59, 175-179.

GHS Hazard and Precautionary Statements

Hazard Statements: H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Precautionary Statements: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
8
Packing Group
II
Harmonized Tariff Code
2904.99
TSCA
No

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