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40177 Dihydrogen hexachloroplatinate(IV) solution, Pt 20% (cont. Pt)

CAS Number
16941-12-1
Synonyms

Stock No. Size Price ($) Quantity Availability
40177-NJ (c)0.5g 161.00
40177-NA (c)2g 570.00
(c)10g Pricing available on request. Click Bulk Quote button and specify size.
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Dihydrogen hexachloroplatinate(IV) solution, Pt 20% (cont. Pt)

MDL
MFCD00011330
EINECS
241-010-7

Chemical Properties

Formula
H2Cl6Pt
Formula Weight
409.82(anhy)
Form
Liquid
Storage & Sensitivity
Ambient temperatures.
Solubility
Miscible with water, alcohol, acetone, ethyl acetate and ether.

Applications

Dihydrogen hexachloroplatinate(IV) is used as a catalyst in the determination of potassium and in the purification of platinum. It is also used in catalysis reactions, electroplating, photography, platinum mirrors, printing for etching of zinc, producing fine color in glass and porcelain, indelible ink and in microscopy. In the presence of copper(II) chloride, it is used to catalyze the photooxygenation of alcohols to aldehydes or ketones. It plays an important role in intramolecular hydrosilylation of an alkyne and hydrosilylation reactions.

Notes

Light, air and moisture sensitive. Incompatible with bases and metals.

Literature References

Wang, J.; Zhao, J.; Osterloh, F. E. Photochemical charge transfer observed in nanoscale hydrogen evolving photocatalysts using surface photovoltage spectroscopy. Energy Environ. Sci. 2015, 8 (10), 2970-2976.

Ghanem, M. A.; Al-Mayouf, A. M.; Shaddad, M. N.; Alhoshan, M. S.; Al-Shalawi, M. N. Chemical Deposition of Nickel Platinum Alloy on the Surface of TiO2 Nanotubes as a Catalyst for Methanol Oxidation. Int. J. Electrochem. Sci. 2015, 10 (4), 3680-3692.

GHS Hazard and Precautionary Statements

Hazard Statements: H301-H314-H317-H334-H335-H372

Toxic if swallowed. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure.

Precautionary Statements: P260-P264b-P270-P271-P272-P280-P285-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. In case of inadequate ventilation wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,7526
Hazard Class
8
Packing Group
III
Harmonized Tariff Code
2843.90
TSCA
Yes

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