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40336 Ruthenium(IV) oxide, Electronic Grade, Premion®, 99.95% (metals basis), Ru typically 74%

CAS Number
12036-10-1
Synonyms
Ruthenium dioxide

Stock No. Size Price ($) Quantity Availability
40336-04 2g 171.00
40336-09 10g 747.00
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Ruthenium(IV) oxide, Electronic Grade, Premion®, 99.95% (metals basis), Ru typically 74%

MDL
MFCD00011210
EINECS
234-840-6

Chemical Properties

Formula
RuO2
Formula Weight
133.07
Form
Sub-micron Powder, Surface Area 45-65m2/g
Melting point
1200° subl.
Density
6.97
Storage & Sensitivity
Hygroscopic. Ambient temperatures.
Solubility
Insoluble in water, acids. Soluble in fused alkalis.

Applications

The most often used oxygen catalyst is ruthenium(IV) oxide. It is applied as an electrochemical super capacitor material, and it has high capacity to store charge. RuO2 is used as catalyst in the Deacon process which produces chlorine through the oxidation of hydrogen chloride. Owing to the high charge transfer capability, it is used as active material in super capacitors. The dispersion property of RuO2 is used to increase the capacitance of nanocomposite electrode materials for supercapacitors. It is extensively used for the coating of titanium anodes, and as a catalyst and doping agent, for use in the removal of hydrogen sulfide from oil refineries.

Notes

Incompatible with oxidizers, acids, aqua regia and organic solvents.

Literature References

Over, H. Surface Chemistry of Ruthenium Dioxide in Heterogeneous Catalysis and Electrocatalysis: From Fundamental to Applied Research. Chem. Rev. 2012, 112 (6), 3356-3426.

Ackermann, L.; Born, R.; Alvarez-Bercedo, P. Ruthenium(IV) Alkylidenes as Precatalysts for Direct Arylations of Alkenes with Aryl Chlorides and an Application to Sequential Catalysis. Angew. Chem. Int. Ed. 2007, 46 (33), 6364-6367.

GHS Hazard and Precautionary Statements

Hazard Statements: H271-H303

May cause fire or explosion; strong oxidizer. May be harmful if swallowed.

Precautionary Statements: P221-P283-P210v-P306+P360-P371+P380+P375-P501a

Take any precaution to avoid mixing with combustibles. Wear fire/flame resistant/retardant clothing. Keep away from heat IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Dispose of contents/container in accordance with local/regional/national/international regulations.

Other References

Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2843.90
TSCA
Yes
RTECS
VM2654000

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