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40579 Scandium(III) perchlorate, 50% w/w aq. soln., Reagent Grade

CAS Number
14066-05-8
Synonyms

Stock No. Size Price ($) Quantity Availability
40579-NA (c)2g 58.50
40579-NC (c)10g 233.00
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Scandium(III) perchlorate, 50% w/w aq. soln., Reagent Grade

MDL
MFCD00243289
EINECS
237-914-6

Chemical Properties

Formula
Sc(ClO4)3•6H2O
Formula Weight
451.42 (343.30anhy)
Form
Liquid
Storage & Sensitivity
Ambient temperatures.
Solubility
Insoluble in water.

Applications

In the presence of a catalytic amount of scandium (III) perchlorate (Sc (ClO 4) 3), 1-O-acetyl-2, 3, 5-tri-O-benzyl-β-D-ribofuranose reacted with trimethylsilylated nucleophiles to afford the corresponding α-D-ribofuranosides in high yields with good selectivities. The condensation of 2,6-diacetylpyridine and m-phenylenediamine in the presence of scandium(III) perchlorate as a template agent affords a new 20-membered macrocyclic complex of formula ScL(C104) 3.4H20 , where L is Me4bzoapyo 2 [20]octaene-N6.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong reducing agents, flammable substances, organic materials, metal powders.

Literature References

Pavel Smirnov,; Hisanobu Wakita,; and Toshio Yamaguchi. X-ray Diffraction Study on Aqueous Scandium(III) Perchlorate and Chloride Solutions over the Temperature Range -45 to 95°C . J. Phys. Chem. B,. 1998, 102 (24), 4802-4808.

Iwao Hachiya,; Shu Kobayashi. Scandium(III) perchlorate (Sc(ClO4)3). A novel catalyst in the α-C- and N-glycosylation reactions . Tetrahedron Letters. 1994, 35 (20), 3319-3320.

GHS Hazard and Precautionary Statements

Hazard Statements: H271-H315-H319-H335

May cause fire or explosion; strong oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P210-P220-P221-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Other References

Hazard Class
5.1
Packing Group
II
Harmonized Tariff Code
2846.90
TSCA
No

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