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40666 Lithium iodide, anhydrous, 99.95% (metals basis)

CAS Number
10377-51-2
Synonyms

Stock No. Size Price ($) Quantity Availability
40666-14 25g 98.60
40666-22 100g 247.00
40666-36 500g 943.00
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Lithium iodide, anhydrous, 99.95% (metals basis)

MDL
MFCD00011092
EINECS
233-822-5

Chemical Properties

Formula
ILi
Formula Weight
133.84
Form
Crystalline/Powder, Ampouled under argon
Melting point
449°
Boiling Point
1170-1190°
Density
4.076
Refractive Index
1.955
Storage & Sensitivity
Hygroscopic. Light Sensitive. Store under Nitrogen. Ambient temperatures.
Solubility
Soluble in water, ethanol and acetone.

Applications

Used as an electrolyte in high temperature batteries and artificial pacemakers. Phosphor , which is a complex of Iodine is used in neuron detection , in an electrolyte of the dye-sensitized solar cell. It is an electrolyte additive for lithium-sulfur batteries.

Notes

LiI should be dried, prior to use in anhydrous reactions.

Literature References

Khanmirzaei, M. H.; Ramesh, S. Ionic transport and FTIR properties of lithium iodide doped biodegradable rice starch based polymer electrolytes. Int. J. Electrochem. Sci. 2013, 8 (7), 9977-9991.

Wu, F.; Lee, J. T.; Nitta, N.; Kim, H.; Borodin, O.; Yushin, G. Lithium Iodide as a Promising Electrolyte Additive for Lithium-Sulfur Batteries: Mechanisms of Performance Enhancement. Adv. Mater. 2015, 27 (1), 101-108.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,5535
Harmonized Tariff Code
2827.60
TSCA
Yes

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