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40752 Copper(I) bromide, Puratronic®, 99.998% (metals basis)

CAS Number
7787-70-4
Synonyms

Stock No. Size Price ($) Quantity Availability
40752-03 1g 65.10
40752-06 5g 235.00
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Copper(I) bromide, Puratronic®, 99.998% (metals basis)

MDL
MFCD00010969
EINECS
232-131-6

Chemical Properties

Formula
CuBr
Formula Weight
143.45
Form
Powder, Ampouled under argon
Melting point
492°
Boiling Point
1345°
Density
4.98
Storage & Sensitivity
Air Sensitive. Store under Argon. Ambient temperatures.
Solubility
Soluble in hydrogen bromide, hydrochloric acid, and ammonium hydroxide. Slightly soluble in water. Insoluble in acetone.

Applications

It is used as effective catalyst for tetrahydropyranylation of alcohols. It can also be used in combination with palladium in catalytic synthesis of 3-haloindoles through annulation process. It is widely used in the synthesis of organic fine chemicals. The compound is widely used in the synthesis of organic compounds. It is also useful for copper-mediated coupling reactions. A silica gel support copper bromide hexa methyltriethylenetetramine complex has shown useful application for the atom transfer radical polymerization of methyl methacrylate in toluene.

Notes

It is a stable, but air or light sensitive chemical compound. Keep container in a cool, well-ventilated area. Do not store above 35°C (95°F) and keep away from incompatibles such as oxidizing agents, alkalis.

Literature References

Shen, Y.; Zhu, S.; Zeng, F.; Pelton, R. H. Atom Transfer Radical Polymerization of Methyl Methacrylate by Silica Gel Supported Copper Bromide/Multidentate Amine. Macromolecules 2000, 33 (15) , 5427-5431.

Evano, G.; Blanchard, N.; Toumi, M. Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis. Chem. Rev. 2008, 108 (8), 3054-3131.

GHS Hazard and Precautionary Statements

Hazard Statements: H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Merck
14,2659
Harmonized Tariff Code
2827.59
TSCA
Yes

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