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41007 Chloro(triphenylphosphine)gold(I), Premion®, 99.99% (metals basis), Au 39.3% min

CAS Number
14243-64-2
Synonyms
Triphenylphosphinegold(I) chloride

Stock No. Size Price ($) Quantity Availability
41007-02 0.5g 102.00
41007-03 1g 159.00
41007-06 5g 668.00
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Chloro(triphenylphosphine)gold(I), Premion®, 99.99% (metals basis), Au 39.3% min

MDL
MFCD00009588
EINECS
238-117-6

Chemical Properties

Formula
AuCl[P(C6H5)3]
Formula Weight
494.71
Form
Powder
Storage & Sensitivity
Ambient temperatures.
Solubility
Soluble in methylene chloride, acetonitrile, benzene and acetone. Insoluble in water and ethanol.

Applications

Chloro(triphenylphosphine)gold(I) is a common reagent in gold chemistry. It catalyzes certain rearrangement reactions in organic synthesis. It is also used to prepare 1-methylthyminato-N3-triphenylphosphinegold(I) by reacting with 1-methylthymine. It acts as a precursor for the synthesis of gold(I) and gold(III) organometallic compounds.

Notes

Incompatible with strong oxidizing agents.

Literature References

Johnson, G. E.; Olivares, A.; Hill, D.; Laskin, J. Cationic gold clusters ligated with differently substituted phosphines: effect of substitution on ligand reactivity and binding. Phys Chem. Chem. Phys. 2015, 17 (22), 14636-14646.

Sakamoto, Y.; Moriuchi, T.; Hirao, T. Organogold(I)-uracil conjugates: Synthesis and structural characterization. J. Organomet. Chem. 2015, 782, 77-81.

GHS Hazard and Precautionary Statements

Hazard Statements: H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Precautionary Statements: P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Other References

Harmonized Tariff Code
2843.30
TSCA
No

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